Conclusions
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1.
The equations for internal diffusion in biporous adsorbents have been analyzed for the case of a rectangular adsorption isotherm.
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2.
A finite adsorption wave front boundary, advancing with the passage of time, is established in microporous adsorbents having a bidispersed structure and a rectangular adsorption isotherm.
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3.
For the case of a rectangular adsorption isotherm, analytical equations relating the moments of the kinetic curve and the function describing the frontal movement have been established.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheakaya, No. 3, pp. 500–505, March, 1977.
The authors would like to thank M. M. Dubinin and A. M. Voloshchuk for valuable suggestions made while discussing this work.
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Zolotarev, P.P., Ulin, V.I. Internal diffusion in a biporous adsorbent having a rectangular adsorption isotherm. Russ Chem Bull 26, 450–454 (1977). https://doi.org/10.1007/BF01179440
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DOI: https://doi.org/10.1007/BF01179440