Skip to main content
Log in

Internal diffusion in a biporous adsorbent having a rectangular adsorption isotherm

I. Formulation of the problem and basic equations

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The equations for internal diffusion in biporous adsorbents have been analyzed for the case of a rectangular adsorption isotherm.

  2. 2.

    A finite adsorption wave front boundary, advancing with the passage of time, is established in microporous adsorbents having a bidispersed structure and a rectangular adsorption isotherm.

  3. 3.

    For the case of a rectangular adsorption isotherm, analytical equations relating the moments of the kinetic curve and the function describing the frontal movement have been established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. P. P. Zolotarev and M. M. Dubinin, Dokl. Akad. Nauk SSSR,210, 136 (1973).

    Google Scholar 

  2. P. P. Zolotarev and V. I. Ulin, Izv. Akad. Nauk SSSR, Ser. Khim., 1648 (1974).

  3. P. P. Zolotarev, Izv. Akad. Nauk SSSR, Ser. Khim., 193 (1975).

  4. A. M. Voloshchuk, P. P. Zolotarev, and V. I. Ulin, Izv. Akad. Nauk SSSR, Ser. Khim., 1250 (1974).

  5. V. I. Ulin, Izv. Akad. Nauk SSSR, Ser. Khim., 2148 (1974).

  6. P. P. Zolotarev and V. I. Ulin, Izv. Akad. Nauk SSSR, Ser. Khim., 2829 (1974).

  7. A. M. Voloshchuk and M. M. Dubinin, Dokl. Akad. Nauk SSSR,212, 649 (1973).

    Google Scholar 

  8. A. M. Voloshchuk, M. M. Dubinin, and I. T. Erashko, Izv. Akad. Nauk SSSR, Ser. Khim., 517 (1975).

  9. M. M. Dubinin, I. T. Erashko, O. Kadlec, V. I. Ulin, A. M. Voloshchuk, and P. P. Zolotarev, Carbon13, 193 (1975).

    Google Scholar 

  10. P. P. Zolotarev, Izv. Akad. Nauk SSSR, Ser. Khim.,700, 711 (1969).

    Google Scholar 

  11. P. P. Zolotarev, Teor. Osnovy Khim. Tekhnol.,4, 603 (1973).

    Google Scholar 

  12. E. Ruckenstein, A. S. Vaidyananthan, and G. R. Youngquist, Chem. Eng. Sci.,26, 1305 (1971).

    Google Scholar 

  13. P. P. Zolotarev, Izv. Akad'. Nauk SSSR, Ser. Khim., 526 (1972).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheakaya, No. 3, pp. 500–505, March, 1977.

The authors would like to thank M. M. Dubinin and A. M. Voloshchuk for valuable suggestions made while discussing this work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zolotarev, P.P., Ulin, V.I. Internal diffusion in a biporous adsorbent having a rectangular adsorption isotherm. Russ Chem Bull 26, 450–454 (1977). https://doi.org/10.1007/BF01179440

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179440

Keywords

Navigation