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Anhydrous zirconium perchlorate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Unsolvated zirconium perchlorate Zr(ClO4)4 has been obtained by the action of ZrCl4 on a solution of C12O7 in HClO4. If anhydrous HClO4 without an excess of Cl2O7 is used as the reagent, a hydrated product is obtained.

  2. 2.

    The IR and Raman scattering spectra of Zr(ClO4)4 indicate the covalent character of the perchlorate group bond and the bidentate type of coordination.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    V. N. Babaeva & V. Ya. Rosolovskii

Authors
  1. V. N. Babaeva
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  2. V. Ya. Rosolovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 495–499, March, 1977.

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Babaeva, V.N., Rosolovskii, V.Y. Anhydrous zirconium perchlorate. Russ Chem Bull 26, 445–449 (1977). https://doi.org/10.1007/BF01179439

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  • DOI: https://doi.org/10.1007/BF01179439

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