Summary
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1.
Polarographic reduction waves of anabasine and N-methylanabasine N-oxides were investigated and the nature of their dependence on solution pH and depolarizer concentration was studied.
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2.
It was established that there is a difference in the nature of the polarographic reduction of N-oxide groups at pyridine and N-methylpiperidine nitrogen, which makes it possible to use polarography to determine the position of an N→ O group in molecules with two tertiary nitrogen atoms differing in character.
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Literature cited
S. G. Mairanovskii and F. S. Titov, Zhur. Anal. Khim.15, 121 (1960).
S. B. Tsfasman, Zavodskaya Lab.22, 131 (1956).
S. G. Mairvanovskii, A. A. Fainzil'berg, S. S. Novikov, and V. A. Klimova, Doklady Akad. Nauk SSSR125, 351 (1959).
E. M. Skobets and N. S. Kavetskii, Zavodskaya Lab.15, 1299 (1949).
V. K. Zvorykina, F. D. Alashev, and Ya. L. Gol'dfarb, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk788 (1958).
S. G. Mairanovskii, N. V. Barashkova, and F. D. Alashev, Zhur. Fiz. Khim. (in press.)
R. Curti and S. Locchi, Atti accad. naz. Lincei Rend. Classe Sci.14, 796 (1953).
A. Foffani and E. Fornasari, Gazz. chim. ital.83, 1051 (1953).
E. Fornasari and A. Foffani, Gazz. chim. ital.83, 1059 (1953).
L. V. Varyukhina and Z. V. Pushkareva, Zhur. Obshch. Khim.26, 1740 (1956).
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Mairanovskii, S.G., Barashkova, N.V., Alashev, F.D. et al. Polarographic study of N-oxides of anabasine and N-methylanabasine. Russ Chem Bull 9, 874–876 (1960). https://doi.org/10.1007/BF01179193
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DOI: https://doi.org/10.1007/BF01179193