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Catalytic hydrocondensation of carbon monoxide with olefins

Communication 28. Activity of a cobalt-clay catalyst in the hydrocondensation of carbon monoxide with ethylene and the hydropolymerization of the latter under the action of carbon monoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Cobalt precipitated on common furnace clay at a ratio of 1: 2 and given a preliminary heating at 450° in a stream of air is an extremely active catalyst in the hydrocondensation of carbon monoxide with ethylene and the hydropolymerization of the latter under the action of carbon monoxide.

  2. 2.

    The oxides of zinc, calcium, and magnesium, and particularly of aluminum, have a promoting effect on this catalyst.

  3. 3.

    The side reaction of the hydrogenation of ethylene can be suppressed to a considerable extent by lowering the hydrogen content of the original gas mixture.

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Literature cited

  1. Ya. T. Éidus, K. V. Puzitskii, and N. I, Ershov, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk 331 (1960).

  2. Ya. T. Éidus, K. V. Puzitskii, and I V. Guseva, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk 2213 (1959).

  3. Ya. T. Éidus, K. V. Puzitskii, and N. I. Ershov, Chemical Processing of Petroleum Hydrocarbons [in Russian] (Izd. AN SSSR, Moscow, 1956) p. 616.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    Ya. T. Éidus, N. I. Ershov, K. V. Puzitskii & I. V. Guseva

Authors
  1. Ya. T. Éidus
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  2. N. I. Ershov
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  3. K. V. Puzitskii
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  4. I. V. Guseva
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Éidus, Y.T., Ershov, N.I., Puzitskii, K.V. et al. Catalytic hydrocondensation of carbon monoxide with olefins. Russ Chem Bull 9, 849–854 (1960). https://doi.org/10.1007/BF01179186

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  • DOI: https://doi.org/10.1007/BF01179186

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