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Organoboron compounds

Communication 56. Synthesis of trialkylborines from metaboric esters and their conversion into dialkylborinic esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Metaboric esters react with alkylmagnesium halides with formation of trialkylborines.

  2. 2.

    When heated with cyclohexanol, benzyl alcohol, 2-octanol, isopentyl alcohol, or phenol, trialkylborines are converted smoothly into the corresponding dialkylborinic esters.

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Literature cited

  1. B. M. Mikhailov and V. A. Vaver, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk 889 (1957).*

  2. G. L. O'Connor and H. R. Nace, J. Am. Chem. Soc.77, 1578 (1955).

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Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    B. M. Mikhailov & V. A. Vaver

Authors
  1. B. M. Mikhailov
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  2. V. A. Vaver
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Additional information

For Communication 52 see Doklady Akad. Nauk SSSR130, 782 (1960); for Communications 53 and 54 see Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk 368, 370 (1960); for Communication 55 see Doklady Akad. Nauk SSSR131, 843 (1960) [see C. B. translations].

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Mikhailov, B.M., Vaver, V.A. Organoboron compounds. Russ Chem Bull 9, 796–799 (1960). https://doi.org/10.1007/BF01179176

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  • DOI: https://doi.org/10.1007/BF01179176

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