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Fluorine-containing β-sultones

Communication 1. Addition of sulfur trioxide to fluoro olefins

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the reactions of tetrafluoroethylene, chlorotrifluoroethylene, trifluoroethylene, and hexafluoropropene with sulfur trioxide.

  2. 2.

    Fluoro olefins and sulfur trioxide (α-modification) react in equimolecular proportions with formation of fluorine-containing β-sultones.

  3. 3.

    The addition of sulfur trioxide to fluoro olefins occurs in the direction corresponding to the polarities of the reactants.

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Literature cited

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Authors
  1. M. A. Dmitriev
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  2. G. A. Sokol'skii
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  3. I. L. Knunyants
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Dmitriev, M.A., Sokol'skii, G.A. & Knunyants, I.L. Fluorine-containing β-sultones. Russ Chem Bull 9, 792–795 (1960). https://doi.org/10.1007/BF01179175

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  • DOI: https://doi.org/10.1007/BF01179175

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