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Summary

  1. 1.

    The rate of reduction of metal ions from 1 N sulfate solutions increases in the following order: nickel, cobalt, iron, zinc, copper, cadmium, thallium, and tin.

  2. 2.

    The rate of anode solution increases in the series: nickel, cobalt, iron, copper, zinc, cadmium, thallium, and tin.

  3. 3.

    The hypothesis is put forward that the different rates of electrochemical reduction of metal ions is connected with the different rates of passivation of the cathode surface during electrolysis.

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Vagramyan, A.T., Popkov, A.P. Overvoltage in the electrodeposition and solution of metals. Russ Chem Bull 9, 765–770 (1960). https://doi.org/10.1007/BF01179171

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  • DOI: https://doi.org/10.1007/BF01179171

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