Summary
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1.
A new method is proposed for determining the activation energy of the chain propagation reaction in chain oxidation reactions with an initiator.
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2.
In the liquid-phase oxidation of acetone, the activation energy of the chain propagation reaction is 15–16 kcal/mole.
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Kh. S. Bagdasar'yan and R. I. Milyutinskaya, Zhur. Fiz. Khim.27, 420 (1953).
N. N. Semenov, Some Problems in Chemical Kinetics and Reactivity [in Russian] (Izd. AN SSSR, Moscow, 1954).
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Denisov, E.T. Oxidation of acetone initiated by benzoyl peroxide. Russ Chem Bull 9, 761–764 (1960). https://doi.org/10.1007/BF01179170
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DOI: https://doi.org/10.1007/BF01179170