Summary
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1.
A new method was found for preparing nitrosyl fluoride, namely, by decomposition of a mixture of nitrosonium pyrosulfate and potassium fluoride.
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2.
A procedure was developed for preparing large amounts of nitrosyl fluoride by continuous gas-phase fluorination of nitric oxide.
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3.
The corrosive action of liquid nitrosyl fluoride on some metals and alloys was studied. The most corrosion-resistant materials are electrolytic nickel and chromium—nickel steel 1Kh-18N-9T.
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Literature cited
O. Ruff and K. Stäuber, Z. Anorgan und allgem. Chem.47, 190 (1905).
O. Ruff, K. Stäuber, and H. Graf, Z. anorgan. und allgem. Chem.58, 325 (1908).
E. Wilke-Dörfurt and G. Balz, Z. anorgan. und allgem. Chem.159, 197 (1926).
O. Ruff, W. Menzel, and W. Neuman, Z. anorgan. und. allgem. Chem.208, 293 (1932).
H. Moussan and P. Lebeau, Compt. rend.140, [24], 1573; [25], 1621 (1905).
A. V. Faloon and W. B. Kenna, J. Am. Chem. Soc.73, 2937 (1951).
C. W. H. Jones, W. J. Price, and H. W. Webb, J. Chem. Soc. 312 (1929).
W. Manchot and H. Schmid, Ber.62, 1261 (1929); W. Manchot, J. König, and S. Reimlinger, Ber.59, 2672 (1926).
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Sokol'skii, G.A., Knunyants, I.L. Preparation of nitrostl fluoride and some of its properties. Russ Chem Bull 9, 731–734 (1960). https://doi.org/10.1007/BF01179165
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DOI: https://doi.org/10.1007/BF01179165