Summary
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1.
The previously deduced equations [1] have been verified quantitatively for the catalytic system quinine-hydrochloric acid.
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2.
The experimental results show that the rate constant for the formation of hydrogen molecules from quinine — hydrogen atom complexes is about 106 times as great as the rate constant for the interaction of quinine and hydroxonium ions.
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Mairanovsky, S.G. Limiting currents associated with the catalytic discharge of hydrogen ions in presence of amines Communication 2. Catalytic effect of quinine. Russ Chem Bull 2, 715–721 (1953). https://doi.org/10.1007/BF01178848
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DOI: https://doi.org/10.1007/BF01178848