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Dipole moments of derivatives of 1, 3, 5,-trinitrobenzen

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The dipole moments of 2, 4, 6-trinitrotoluene, 2, 4, 9-trinitro-m-xylene, and styphnic acid were measured.

  2. 2.

    The high values found for trinitrotoluene and trinitro-m-xylene are to be explained by the influence of the nitro groups.

  3. 3.

    It was shown that in these cases it is essential to take atom polarization into account.

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Literature Cited

  1. C. Le Fevre, R. Le Fevre, J. Chem. Soc., 1950, 1829.

  2. C. Cartwright, J. Errera, Acta Phys. Chim. USSR, 3, 649 (1935).

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  3. J. Coop, L. Sutton, J. Chem. Soc., 1938, 1269.

  4. E. Shott-Lvova and Ya. Syrkin, Acta Phys. Chim. USSR 11, 659, (1939).

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  5. E. Caldin, G. Long, Nature 171, 1124 (1953).

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Authors and Affiliations

  1. M. V. Lomonosov Institute of Fine Chemical Technology, Moscow

    E. A. Shott-Lvova & Ya. K. Syrkin

Authors
  1. E. A. Shott-Lvova
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  2. Ya. K. Syrkin
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Shott-Lvova, E.A., Syrkin, Y.K. Dipole moments of derivatives of 1, 3, 5,-trinitrobenzen. Russ Chem Bull 5, 119–120 (1956). https://doi.org/10.1007/BF01178023

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  • DOI: https://doi.org/10.1007/BF01178023

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