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Macromolecular compounds Communication 90. Polycondensation of 1,2-dichloroethane with tetralin

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the polycondensation of 1,2-dichloroethane with tetralin in presence of aluminum chloride, and the main features of the process were established.

  2. 2.

    On the basis of X-ray-structure analysis it was established that the product formed in the first stage of the polycondensation of 1,2-dichloroethane with tetralin is 1,2-di-2-tetralylethane [1,2-bis(5,6,7,8-tetrahydro-2-naphthylethane].

  3. 3.

    It was found that no three-dimensional products are formed in the polycondensation of 1,2-dichloroethane with tetralin, in spite of the fact that the potential functionality of retralin is four.

  4. 4.

    It was shown that the polymer [poly(ar-ethylenetetralyl) does not undergo association in benzene solution at concentration of up to 10 g per 100 ml.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    G. S. Kolesnikov, V. V. Korshak, M. A. Andreeva & A. I. Kitaigorodsky

Authors
  1. G. S. Kolesnikov
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  2. V. V. Korshak
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  3. M. A. Andreeva
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  4. A. I. Kitaigorodsky
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Kolesnikov, G.S., Korshak, V.V., Andreeva, M.A. et al. Macromolecular compounds Communication 90. Polycondensation of 1,2-dichloroethane with tetralin. Russ Chem Bull 5, 107–111 (1956). https://doi.org/10.1007/BF01178021

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  • DOI: https://doi.org/10.1007/BF01178021

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