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Hydrogenation of isopropenylcyclopropane in presence of palladium black

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1

    It was found that in the hydrogenation of isopropenylcyclopropane in alcohol solution in presence of palladium black at room temperature and atmospheric pressure two molecular proportions of hydrogen. formation of 2-methylpentane.

  2. 2.

    It was shown that the hydrogenation of isopropenyleycyclopropane proceeds through the latermediate formation of 2-methyl-1-pentene and 2-methyl-2-pentene.

  3. 3.

    It was found that, under the hydrogenation conditions used, reversible isomerization of 2-methyl-2-pentene into 2-methyl-1-pentene occurs.

  4. 4.

    It was shown that isopropenylcyclopropane remains unchanged when shaken for a long time with reduced palladium black.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    B. A. Kazansky, M. Yu. Lukina, A. I. Malyshev, V. T. Aleksanyan & Kh. E. Sterin

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  1. B. A. Kazansky
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  2. M. Yu. Lukina
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  3. A. I. Malyshev
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  4. V. T. Aleksanyan
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  5. Kh. E. Sterin
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Kazansky, B.A., Lukina, M.Y., Malyshev, A.I. et al. Hydrogenation of isopropenylcyclopropane in presence of palladium black. Russ Chem Bull 5, 35–41 (1956). https://doi.org/10.1007/BF01178010

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  • DOI: https://doi.org/10.1007/BF01178010

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