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Oxidation-reduction systems for the initiation of free-radical processes Communication 1. Reversible systems in which organic hydroperoxides, dienols, and salts of metals of variable valence take part

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the mechanism of the action of reversible oxidation-reduction systems consisting of an organic hydroperoxide, a dienol, and an iron or copper salt.

  2. 2.

    It was shown that it is possible to use these systems for the initiation of polymerization at low temperatures.

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Literature cited

  1. V. A. Kozlov and B. V. Ptitsyn, J. Anal. Chem. 4, 35 (1949).

    Google Scholar 

  2. H. W. Laundrie, F. Cann, Ind, Eng. Chem. 41, 8, 1568 (1949).

    Google Scholar 

  3. C. Marvel, R. Deanin, J. Pol. Sci. 3, 1, 123 (1948).

    Google Scholar 

  4. B. A. Dolgoplosk and E. A. Kropacheva, J. Gen. Chem. 26, 11, 2890 (1956.

    Google Scholar 

  5. D. M. Mikhlin, Peroxides and Peroxidases, 1948, Acad. Sci. USSR Press.

  6. M. A. Bodin, Fact. Lab. 8, 32 (1939).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Compounds of the Academy of Sciences of the USSR, USSR

    G. P. Belonovskaya, B. A. Dolgoplosk & E. I. Tinyakova

Authors
  1. G. P. Belonovskaya
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  2. B. A. Dolgoplosk
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  3. E. I. Tinyakova
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Belonovskaya, G.P., Dolgoplosk, B.A. & Tinyakova, E.I. Oxidation-reduction systems for the initiation of free-radical processes Communication 1. Reversible systems in which organic hydroperoxides, dienols, and salts of metals of variable valence take part. Russ Chem Bull 5, 1521–1528 (1956). https://doi.org/10.1007/BF01177534

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  • DOI: https://doi.org/10.1007/BF01177534

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