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Polyenic compounds Communication 2. Polyenic compounds containing heterocyclic substituents

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In the reactions of 2-pyridylmethyllithium and of 2-quinolylmethyllithium with 3-methyl-6-phenyl-3, 5-hexadien-2-one, the corresponding tertiary alcohols were formed. Dehydration of these gave 2, 3-dimethyl-6-phenyl-1-(2-pyridyl)-1, 3, 5-hexatriene and 2, 3-dirnethyl-6-phenyl-1-(2-quinolyl)-1, 3, 5-hexatriene.

  2. 2.

    Reaction of 2-pyridylmethyllithium and of 2-quinolylmethyllithium with cinnamaldehyde gave the butenols 4-phenyl-1-(2-pyridyl)-3-buten-2-o1 and 4-phenyl-1-(2-quinolyl)-3-buten-2-o1. 'Dehydration of these gave butadiene derivatives.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    B. M. Mikhailov & G. S. Ter-Sarkisyan

Authors
  1. B. M. Mikhailov
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  2. G. S. Ter-Sarkisyan
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Mikhailov, B.M., Ter-Sarkisyan, G.S. Polyenic compounds Communication 2. Polyenic compounds containing heterocyclic substituents. Russ Chem Bull 5, 1489–1492 (1956). https://doi.org/10.1007/BF01177529

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  • DOI: https://doi.org/10.1007/BF01177529

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