Summary
It was shown that the breakdown of hydrogen disulfide in a-olefins results in the exclusive formation of addition products (mono-, di-, and tetra-sulfides) without formation of hydrogen sulfide and free sulfur.Similar results were obtained when sulfur reacted with monoethanolamine (vulcanization accelerator) in α-olefin solution.
The reaction products were isolated and characterized.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
E. I. Tinyakova, E. K. Khrennikova, B. A. Dolgoplosk, and V. N. Reikh, J. Gen. Chem. 26, 2476 (1956).
Bloch and Hohn, Ber. 41, 1961 (1908).
Bloch and Hohn, Ber. 41, 1975 (1908).
B. A. Kazansky et al., J. Gen. Chem. 17, 1505 (1947).
V. V. Gurova and B. V. Bolotnikov, J. Rubber Ind. 1933, No. 6, 61.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tinyakova, E.I., Khrennikova, E.K. & Dolgoplosk, B.A. Role of hydrogen disulfide in the vulcanization process. Russ Chem Bull 5, 1179–1181 (1956). https://doi.org/10.1007/BF01177375
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01177375