Summary
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1.
The following organogermanium compounds containing unsaturated radicals were prepared for the first time:
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2.
It was shown that, in presence of benzoyl peroxide, sulfuryl chloride chlorinates trichloroethylgermane with formation of a 1 : 9 mixture of trichloro(1-chloroethyl)- and trichloro(2-chloroethyl)-germ anes.
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3.
It was found that quinoline readily eliminates HCl from trichloro(2-chloroethyl)germane with formation of trichlorovinylgermane.
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Petrov, A.D., Mironov, V.F. & Golgy, I.E. Synthesis of unsaturated organogermanium compounds. Russ Chem Bull 5, 1169–1172 (1956). https://doi.org/10.1007/BF01177372
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DOI: https://doi.org/10.1007/BF01177372