Summary
-
1.
As it is found that, under the given dehydrogenation conditions, cyclohexane hydrocarbons apparently undergo no appreciable change in structure, it may be considered that the aromatic hydrocarbons obtained correspond to the naphthene hydrocarbons.
-
2.
-
a)
alkyl derivatives of cyclohexane, including branched-chain monoalkyl derivatives, p- and m-dialkylcyclohexanes, 1,3,5- and 1,2,4-trialkyl derivatives, and tetraalkyl derivatives, mainly 1,2,3,4 and 1,2,3,5; the possibility of the presence of penta- and hexa-methylcyclohexanes cannot be excluded;
-
b)
hydrogenated acenaphthene (found in Tuimazin petroleumn for the first time);
-
c)
decalin and its homologs (about 1% on the total amount of the fractions).
-
a)
-
3.
No bieyclohexyl and its homologs were detected in the kerosene of Tuimazin petroleum.
Similar content being viewed by others
Literature cited
Z. T. Zonova, Investigation of the Chemical Composition of the Catalytic-cracking Product from the Middle Fraction of Baltic-coast Shale Tar, Candidate's Thesis. (Inst. Min. Fuels Acad. Sci. USSR, 1954).
N. D. Zelinsky, J. Russ. Chem. Soc. 43, 1220 (1911).
L. M. Rozenberg, I. S. Genekh, and P. A. Nikitina, Azerbaidzhan Petroleum Industry 12, 18 (1953).
N. G. Adams, D. M. Richardson, Anal. Chem. 23, 129 (1951).
W. Cocker, B. E. Gross and J. Mc. Cormick, J. Chem. Soc. 1952, 72.
G. F. Seidel, P. H. Müller and H. Schinz, Helv. Chim. Acta 27, 738 (1944).
R. P. Liriswa , K. O. Michaelis and S. L. Thomos, J. Chem. Soc. 1940, 1193.
Ya. I. Denisenko and A. F. Nabor, J. Gen. Chem. 10, 193 (1940).
L. M. Rozenberg and S. S. Nifontva, Trans. All- Union Confer. Confer. Chem. Refining Petroleum (Acad. Sci. Azerbaidzhan S.S.R. Press, Baku, 1953), p. 136.
G. Egloff, Physical Constants of Hydrocarbous(Reinhold Publishing Corp., New York, 1946).
Hans Meyer, Analysis and Determination of Organic Compounds (United Sci. Tech. Press, Chem. Theor. Series, Leningrad, 1937), p. 216.
H. Conrad-Billroth, Z. physik. Chem. 29, 170 (1935).
M. S. Norris and N. D. Coggeshell, Anal. Chem. 25, 183 (1953).
M. Pestemer and O. Gübitz, Monatsch. 04,48G (1954).
R. Stair, J. Research NBS 42, 6, 587 (1948).
R. R. Gordon, H. Powell, J. Inst. Petrol, 51, 263, 439 (1945).
A. ROthen and P.A. Levens, J. Chem. Phys. 7, 11, 981 (1939).
F. W. Melpolder, and I. E. Woodbridge, J. Am. Chem. Soc. 70, 935 (1948).
H. Pines, and G. I. Czajkowski, J. Am. Chem. Soc. 71, 3799 (1949).
Th. F. Braedley and D. Richardson, Ind. Eng. Chem., Ind. Ed. 32, 965 (1948).
R. A. Friedel, and M. Orchin, Ultraviolet Spectra of Aromatic Compounds (N.Y., 1951).
H. Sheppard, J. Inst. Petr. 37,327, 95 (1951).
K. Kohlrausch, Raman Spectra (Foreign Lit. Press, 1952), p. 829.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Topchiev, A.V., Rozenberg, L.M., Kusakov, M.M. et al. Investigation of the composition of the naphthene part of the kerosene fraction of tuimazin (Devonian) petroleum. Russ Chem Bull 5, 1127–1135 (1956). https://doi.org/10.1007/BF01177366
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01177366