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The catalytic hydrocondensation of carbon monoxide with olefins

Communication 7. Effect of the carbon monoxide concentration on the hydrocondensation reactions of carbon momnoxide with propene and with n-butene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    An investigation has been made into the effect of the concentration of carbon monoxide on its hydrocondensation with propene and with n-butene.

  2. 2.

    It has been established that, in absence of carbon monoxide, hydrocondensation does not occur in propene — hydrogen and butene — hydrogen mixtures.

  3. 3.

    The highest rate for the reaction of the hydrocondensation of propene or butene with carbon monoxide occurs when 6–8% of the latter is present in the original gas mixture.

  4. 4.

    When the carbon monoxide concentration in the original mixture is 15–20%, the process of hydrocondensation with propene or butene is greatly retarded; this stands in contrast to th course of the process of hydrocondensation with ethylene.

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Literature cited

  1. Ya.T.Eydus, N.D.Zelinsky, N.I.Ershov, and M.I.Batuev, Bull. Acad. Sci. USSR, 6, 731 (1951).

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Authors and Affiliations

  1. Institute of Organic Chemistry of the USSR Academy of Sciences, Russia

    Ya. T. Eydus, N. D. Zelinsky, K. V. Puzitsky & N. I. Ershov

Authors
  1. Ya. T. Eydus
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  2. N. D. Zelinsky
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  3. K. V. Puzitsky
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  4. N. I. Ershov
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Eydus, Y.T., Zelinsky, N.D., Puzitsky, K.V. et al. The catalytic hydrocondensation of carbon monoxide with olefins. Russ Chem Bull 1, 157–163 (1952). https://doi.org/10.1007/BF01176584

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  • DOI: https://doi.org/10.1007/BF01176584

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