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Synthesis of aromatic organo-antimony compounds by the aid of arylazoformates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A method has been developed for the synthesis of aromatic organo-antimony compounds by way of arylazoformates.

  2. 2.

    A. mechanism has been proposed for the reactions considered.

  3. 3.

    It has been found that, under the action of antimony tri- or pentachloride, arylazoformates may be converted into aromatic diazonium salts.

  4. 4.

    A convenient preparative method is proposed for the production of diphenylstibinic acids, which are not readily accessible; it consists in the decomposition of the ouble salt of benzenediazonium chloride and antimony tri-chloride by means of zinc.

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Authors
  1. O. A. Reutov
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  2. O. A. Ptitsyna
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Reutov, O.A., Ptitsyna, O.A. Synthesis of aromatic organo-antimony compounds by the aid of arylazoformates. Russ Chem Bull 1, 103–112 (1952). https://doi.org/10.1007/BF01176578

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  • DOI: https://doi.org/10.1007/BF01176578

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