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New method of synthesizing trialkoxititanium chlorides

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A new method is proposed for the synthesis of trialkoxytitanium chlorides by transesterification of the readily accessible triethoxytitanium chloride according to the equation:

    $$(C_2 H_5 O)_3 TiCl + 3ROH \rightleftarrows (RO)_3 TiCl + 3C_2 H_5 OH.$$
  2. 2.

    The following previously unknown trialkoxytitanium chlorides have been synthesized:

    (n−C4H9O)3TiCl,

    b.p. 154–155°/2 mm

    (i−C4H9O)3TiCl,

    b.p. 147–148°/5 mm

    (i−C5H11O)3TiCl,

    b.p. 173–175°/2 mm

    (n−C6H13O)3TiCl,

    b.p. 182–182.5°/1 mm

    (ClCH2CH2O)3TiCl,

    b.p. 194–196°/2 mm

    (C2H5OCH2CH2O)3TiCl

    b.p. 182–183°1 mm

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Literature cited

  1. J. S. Jennings, Wardlaw, Way, J. Chem. Soc. 637 (1956).

  2. O. V. Nogina, R. Kh. Freidlina, and A. N. Nesmeyanov, Bull. Acad. Sci. U.S.S.R. Div. Chem. Sci.,3 327 (1950)

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  3. A. N. Nesmeyanov, R. Kh. Freidlina, and O. V. Nogina. Bull. Acad. Sci. U.S.S.R. Div. Chem. Sci.,5, 518 (1951)

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Authors and Affiliations

  1. Institute of Organic Chemistry of the U.S.S.R. Academy of Sciences, Russia

    O. V. Nogina, R. Kh. Freidlina & A. N. Nesmeyanov

Authors
  1. O. V. Nogina
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  2. R. Kh. Freidlina
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  3. A. N. Nesmeyanov
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Nogina, O.V., Freidlina, R.K. & Nesmeyanov, A.N. New method of synthesizing trialkoxititanium chlorides. Russ Chem Bull 1, 81–85 (1952). https://doi.org/10.1007/BF01176575

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  • DOI: https://doi.org/10.1007/BF01176575

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