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Synthesis and reactions of oxygen-containing organosilicon compounds

Communication 6. Reaction of alcohols with alkyl- and aryl-dichlorosilanes containing silicon-attached hydrogen

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It was shown that reaction between alkydichlorosilanes containing silicon-attached hydrogen and alcohols in a ratio of 1 : 1 gives mainly alkoxyalkylhalosilanes RSiH (Cl) (OR???), for a ratio of 1 : 2 it gives mainly dialkoxyalhylsilanes RSiH(OR???)2, and for a ratio of 1 : 3 and for an excess of the alcohol it gives mainly trialkoxyalkylsilanes RSi (OR???)3.

  2. 2.

    The silicon-attached hydrogen atom of such alkylhalosilanes is readily converted into an alkoxy group.

  3. 3.

    A stepwise esterification scheme is proposed which is valid for alkyl-and aryl-halosilanes containing silicon-attached hydrogen.

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Literature Cited

  1. M. F. Shostakovsky and D. A. Kochkin, Proc. Acad. Sci. USSR 1069, NO. 1, 113 (1956)(T.p. 363).

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  2. M. F. Shostakovsky and D. A. Kochkin, and V. M. Rogov, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956, 1062(T.p. 1079).

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  3. R. O. Sauer, J. Am. Chem. Soc. 68, 138 (1946).

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  4. H. W. Post and Ch. H. Hofrichter, J. Org. Chem. 5, 443 (1940).

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  5. K. A. Andrianov and D. A. Kochkin, Authors' Certificate No. 71050 (1947); Inventions Bull. 1948, No. 4,16; Authors' Certificate No. 9517 (1949).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    M. F. Shostakovsky, D. A. Kochkin, V. L. Vinogradov & V. A. Neterman

Authors
  1. M. F. Shostakovsky
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  2. D. A. Kochkin
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  3. V. L. Vinogradov
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  4. V. A. Neterman
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Additional information

A previous communication by this school of authors under the same general title is also numbered 6 (Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956, 1062; C. B. pagination 1079)-Publisher.

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Shostakovsky, M.F., Kochkin, D.A., Vinogradov, V.L. et al. Synthesis and reactions of oxygen-containing organosilicon compounds. Russ Chem Bull 5, 1301–1304 (1956). https://doi.org/10.1007/BF01173791

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  • DOI: https://doi.org/10.1007/BF01173791

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