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Oligomerization

Communication 1. Reaction of some vinyl ethers with carbon tetrachloride

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1

    A study was made of the conditions under which carbon tertrachloride reacts with phenyl vinyl, butyl vinyl, and ethyl ethers in presence of benzoyl peroxide.

  2. 2.

    It was found that, in presence of benzoyl peroxide, vinyl ethers are able to react with carbon tetrachloride with formation of both equimolecular-addition products and polymetric products, depending on the original proportions of reactants.

  3. 3.

    The characteristics of the resulting phenyl, ethyl, and butyl 1,3,3,3-tetrachloropyl ethers were determined. Their hydrolytic decomposition was studied, and it was shown that, in the case of the phenyl ether, it can provide a quantitative method for the determination of the concentration of the ether.

  4. 4.

    The mobility of α-chloro in the 1,3,3,3-tetrachloropyl ethers was demonstrated in hydrolytic-scission reactions and in the exchange reaction with an alcohol.

  5. 5.

    The polymeric products form by addition of carbon tetrachloride to phenyl vinyl, ethyl vinyl, and butyl vinyl ethers were isolated and characterized.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    M. F. Shostakovsky, A. V. Bogdanova, M. M. Zverov & G. I. Plotnikova

Authors
  1. M. F. Shostakovsky
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  2. A. V. Bogdanova
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  3. M. M. Zverov
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  4. G. I. Plotnikova
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Shostakovsky, M.F., Bogdanova, A.V., Zverov, M.M. et al. Oligomerization. Russ Chem Bull 5, 1263–1268 (1956). https://doi.org/10.1007/BF01173785

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  • DOI: https://doi.org/10.1007/BF01173785

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