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Condensation of 2-Chlorovinyl ketones with benzene and its homologs

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A new method was developed for the synthesis of styryl ketones. It consists in the condensation of 2-chlorovinyl ketones with aromatic hydrocarbons in presence of aluminum chloride and moist hydrogen chloride.

  2. 2.

    It was shown that 1,4-dichloro-3-buten-2-one is extremely reactive in this reaction.

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Nesmeyanov, A.N., Rybinskaya, M.I. & Kochetkov, N.K. Condensation of 2-Chlorovinyl ketones with benzene and its homologs. Russ Chem Bull 5, 1225–1228 (1956). https://doi.org/10.1007/BF01173779

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  • DOI: https://doi.org/10.1007/BF01173779

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