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Synthesis and reactions of unsaturated organosilicon compounds

Communication 5. Synthesis of mixed diacetylenic organosilicon glycols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Summary

  1. 1.

    A method was developed for the preparation of mixed diacetylenic organosilicon glycols. Five such glycols were prepared for the first time: 4,4′-(methylphenylsilylene)-, 4,4′-(ethylphenylsilylene)-, 4,4′-(diphenylsilylene)-, 4,4′-(diethylsilylene)-, and 4,4′-(methylnaphthylsilylene)-bis[2-methyl-3-butyn-2-ol).

  2. 2.

    The presence of hydroxy groups in the mixed organosilicon glycols was proved by the synthesis of the corresponding acetyl derivatives (VI).

  3. 3.

    4,4′-(Methylphenylsilylene)bis[2-methyl-3-butyn-2-ol] diacetic ester and 4,4′-(methylphenylsilylene)-bis[2-methyl-2-butanol] were prepared and characterized for the first time.

  4. 4.

    The presence of two triple bonds in the glycols was proved by quantitative catalytic hydrogenation to the corresponding saturated compounds.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    I. A. Shikhiev & L. A. Kayutenko

Authors
  1. I. A. Shikhiev
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  2. L. A. Kayutenko
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Shikhiev, I.A., Kayutenko, L.A. Synthesis and reactions of unsaturated organosilicon compounds. Russ Chem Bull 6, 1016–1019 (1957). https://doi.org/10.1007/BF01173601

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  • DOI: https://doi.org/10.1007/BF01173601

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