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Copolymerization of chloroprene with vinyl esters

Communication 1

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Conditions were found for the preparation of the previously undescribed copolymers of chloroprene with vinyl formate, vinyl acetate, vinyl propionate, and vinyl butyrate.

  2. 2.

    The copolymerization constants r1 and r2 were determined for vinyl formate, vinyl acetate, vinyl propionate, and vinyl butyrate in reaction with chloroprene at 65° with the aid of the method of the “selected curve.”

  3. 3.

    Relative activities with respect to the chloroprene radical were calculated for these vinyl esters.

  4. 4.

    Integral and differential compositions were calculated for copolymers of chloroprene with vinyl for mate.

  5. 5.

    Some of the properties of the copolymers were determined.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds of the Academy of Sciences of the USSR, USSR

    S. N. Ushakov & L. B. Trukhmanova

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  1. S. N. Ushakov
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  2. L. B. Trukhmanova
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Ushakov, S.N., Trukhmanova, L.B. Copolymerization of chloroprene with vinyl esters. Russ Chem Bull 6, 1004–1012 (1957). https://doi.org/10.1007/BF01173599

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  • DOI: https://doi.org/10.1007/BF01173599

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