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Organosilicon esters of organosilicon acids

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Five new organosilicon esters of organosilicon acids were prepared by the transacylation of trialkylsilyl propionates with mono- and di-basic organosilicon acids.

  2. 2.

    For use as intermediaries we synthesized (diethylmethylsilyl)propionic acid, diethyl [(diethylmethylsilyl]methyl]malonate, and 3,3′-(tetraethyldisiloxanylene)dipropionic acid.

  3. 3.

    It was shown that treatment of (diethylmethylsilyl)propionic acid with concentrated sulfuric acid at room temperature results in rupture of the CH3-Si bond and formation in good yield of 3,3′-(tetraethyldisilox-anylene)dipropionic acid.

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Literature cited

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Authors and Affiliations

  1. Institute of Silicate Chemistry of the Academy of Sciences of the USSR, USSR

    B. N. Dolgov, E. V. Kukharskaya & D. N. Andreev

Authors
  1. B. N. Dolgov
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  2. E. V. Kukharskaya
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  3. D. N. Andreev
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Dolgov, B.N., Kukharskaya, E.V. & Andreev, D.N. Organosilicon esters of organosilicon acids. Russ Chem Bull 6, 994–996 (1957). https://doi.org/10.1007/BF01173596

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  • DOI: https://doi.org/10.1007/BF01173596

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