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Ionic and free-radical polymerization and copolymerization of vinyl ethers of cyclohexanol, dec ahydro-2-naphthol, and 2-naphthol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    As a result of the study of the polymerization and copolymerization of cyclohexyl vinyl, decahydro-2-naphthyl vinyl, and 2-naphthyl vinyl ethers by the ionic and free-radical mechanisms, the conditions were found for the preparation in good yield of their polymers and their copolymers with ethyl vinyl, butyl vinyl, and phenyl vinyl ethers, which were obtained in presence of boron trifluoride.

  2. 2.

    The conditions were found for the preparation of polymers in presence of benzoyl peroxide and of 2,2′-azobis [2-methylpropionitrile], and also for the preparation of copolymers of the vinyl ethers with methyl esters of acrylic and methacrylic acids in presence of benzoyl peroxide.

  3. 3.

    The vinyl ether contents of the copolymers depend on the initial monomer ratios.

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Literature Cited

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Authors and Affiliations

  1. N. D. Zelinsky Institute of organic Chemistry of the Academy of Sciences of the USSR, USSR

    A. V. Bogdanova, M. F. Shostakovsky & G. K. Krasilnikova

Authors
  1. A. V. Bogdanova
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  2. M. F. Shostakovsky
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  3. G. K. Krasilnikova
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Bogdanova, A.V., Shostakovsky, M.F. & Krasilnikova, G.K. Ionic and free-radical polymerization and copolymerization of vinyl ethers of cyclohexanol, dec ahydro-2-naphthol, and 2-naphthol. Russ Chem Bull 6, 396–398 (1957). https://doi.org/10.1007/BF01173348

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  • DOI: https://doi.org/10.1007/BF01173348

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