Summary
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1.
Reduction of vinyl-, phenyl-, and alkyl-chlorosilanes with the aid of lithium hydride gave various vinyl-, phenyl-, and Alkyl-silanes.
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2.
The Raman spectra of compounds of formula HSiR3, H2SiR2, and H3SiR ( R is an aliphatic radical ) show that the quasielastic constant of the Si — H bond diminishes as the number of silicon-attached hydrogen atoms diminishes.
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3.
The dehydrochlorination of some alkyl (2-chloroethyl)silanes and an analogous disilabutane derivative was studied, and it was shown that there is a relationship between the dehydrochlorination reaction and the accompanying β -decomposition reaction.
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4.
It was shown that chlorosilyl groups have a stabilizing action in the dehydrochlorination reaction and, as chlorine atoms accumulate on silicon, the yield of β -decomposition products falls and the yield of dehydro-chlorination products rises; there is also a reduction in the reactivity of α-chloro compounds.
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Petrov, A.D., Ponomarenko, V.A., Sokolov, B.A. et al. Synthesis and properties of some vinyl-,phenyl-,and alkyl-silanes containing silicon-attached hydrogen. Stabilizing effect of chlorosilyl groups. Russ Chem Bull 6, 323–331 (1957). https://doi.org/10.1007/BF01173336
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DOI: https://doi.org/10.1007/BF01173336