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An efficient method for the preparation of perfluoroacyl iodides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The direct halodefluorination of perfluoroacyl fluorides holds considerable interest in both synthetic and theoretical studies. However, the great strength of the C-F bond at the carbonyl carbon atom in comparison with the analogous C-Cl and C-Br hinders such transformations [1, 2]. In the case of iododefluorination, such reactions have not even been reported.

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Literature cited

  1. J. D. La Zert, W. H. Pearlson, and E. A. Kauck, US Patent No. 2,704,776; Ref. Zh. Khim., 12587P (1955).

  2. I. L. Knunyants, Yu. A. Cheburkov, and M. D. Baranova, Izv. Akad. Nauk SSSR, Ser. Khim., 1393 (1963).

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Authors and Affiliations

  1. Fine Organic Synthesis Section, Institute of Chemistry, Bashkir Science Center, Urals Branch, Academy of Sciences of the USSR, Sverdlovsk

    I. K. Bil'dinov, L. E. Deev, K. I. Polikevich, P. V. Podsevalov, N. A. Sal'nikova & V. G. Ponomarev

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  1. I. K. Bil'dinov
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  2. L. E. Deev
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  3. K. I. Polikevich
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  4. P. V. Podsevalov
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  5. N. A. Sal'nikova
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  6. V. G. Ponomarev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, p. 1932, August, 1991.

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Bil'dinov, I.K., Deev, L.E., Polikevich, K.I. et al. An efficient method for the preparation of perfluoroacyl iodides. Russ Chem Bull 40, 1718 (1991). https://doi.org/10.1007/BF01172283

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  • DOI: https://doi.org/10.1007/BF01172283

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