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Quantitative evaluation of the effect of the medium on the thermodynamic parameters of conformational transitions of substituted 1,3-dioxanes in solutions and gases with PMR data

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

It was shown that the reaction field model satisfactorily describes the thermodynamic parameters of conformational equilibrium of 2-acetyl-substituted 1,3-dioxanes both as a function of the properties of the solvent and the phase state of the compound studied. Quantitative agreement was obtained between the experimental and theoretical values.

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan' State University, USSR

    Sh. K. Latypov, V. V. Klochkov, A. V. Il'yasov & A. V. Aganov

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Academy of Sciences of the USSR, USSR

    Sh. K. Latypov, V. V. Klochkov, A. V. Il'yasov & A. V. Aganov

Authors
  1. Sh. K. Latypov
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  2. V. V. Klochkov
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  3. A. V. Il'yasov
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  4. A. V. Aganov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1782–1789, August, 1991.

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Latypov, S.K., Klochkov, V.V., Il'yasov, A.V. et al. Quantitative evaluation of the effect of the medium on the thermodynamic parameters of conformational transitions of substituted 1,3-dioxanes in solutions and gases with PMR data. Russ Chem Bull 40, 1577–1583 (1991). https://doi.org/10.1007/BF01172254

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  • DOI: https://doi.org/10.1007/BF01172254

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