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Macromolecular compounds

Communication 84. Polycondensation of 1.2-dichloroethane with toluene ane with toluene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study vat made of the polycoodensation of 1,2-dichloroethane with toluene with formation of poly(ethylenetolyl) The low-molecular-weight products of this reaction were ar,ar- dimethylbibenzyl and bis(2-tolylethyl) toluene.

  2. 2.

    The structure of the polycondensation products formed from 1,2-dichloroethane and toluene was established

  3. 3.

    It was shown that the cause of the greater difficulty with which three-dimensional polymers are nal polymers are formed in the polycondensation of 1;2-dichloroethane witb toluene— as compared with the analogous reaction between 1,2-dichloroethane and chlorobenzene— it the m an arrangement of substituents oriented predominantly meta to one another.

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Literature Cited

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Koleinikov, G.S., Korshak, V.V. & Soboleva, T.A. Macromolecular compounds. Russ Chem Bull 4, 1007–1010 (1955). https://doi.org/10.1007/BF01172125

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  • DOI: https://doi.org/10.1007/BF01172125

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