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Summary

  1. 1.

    Trihexylmethyl-, methyltrioctyl-, tridecylmethyl-silianes] which have not been desctlbed previously is the literature, were synthesized.

  2. 2.

    Parachors were determined for 2 series of trialkylmethylsilanes, ranging from triethyl- to tridecyl-methyl-silanes.

  3. 3.

    The parachor data indicate that trialkylmethylsilanes probably have extended structures in which two chains lie parallel, similar to the structure (also derived from parachor data) of orthopropionic esters, in which there is also an absence of any kind of polarity in the cenual atom.

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Literature cited

  1. T. W. Gibling, J. Chem. Soc., 1944, 380.

  2. B. A. Arbuzov and V. S. Vinogradova. Bull. Acad. Sci. USSR, Div. Chem. Sel., 1951, No. 6 733, 1. Phys Chem. 22. 303 (1948) . Proc. Acad. Scl. USSR. 60, 779 (1948) ; V. S. Vinogradova, Sel. Memoirs Kazan Slate Univ. 110, (9), 1950, p. b,

  3. B. A. Arbuzov and L. M. Guzhavina, Proc. Acad. Sci. USSR., 61, 63 (1941) ; B, A. Arbuzov and L. M. Katzeva J. Phys. Chem. 26, 1298 (1952).

    Google Scholar 

  4. K. L Yuzmin and G. Kamai, Collection of Papers on General Cbemisuy, Acad. Sci., USSR Press. Moscow and Leningrad, 1953, 1, 223–2211.

    Google Scholar 

  5. O. R. Quayle, Chem. Rev., 53, 439 (1953).

    Google Scholar 

  6. S. A. Mumford. J. W. C. Phillips, J. Chem. Soc., 1929, 2112.

  7. E. L Warrick, J. Am. Chem. Soc., 68, 2455 (1946).

    Google Scholar 

  8. F. C. Whitmore, L. H. Sommer, P. A. DiGiorgio, W. A. Strong, J. Am. Chem. Soc., 68, 475 (1946).

    Google Scholar 

  9. C. Morn, J. Cbem. Soc.. 1949, 2755.

  10. Larsson van Gilse van der Pals, Chem. Abs.. 1952, 2516.

  11. T. W. Gibling. J. Chem. Soc., 1945, 239.

  12. W. J. Jones, L H. Thomas, E. K Pritchard, S. T. Bowden. J. Cher. Soc., (3945), 824.

  13. H. Gilman and G. E. Dunn, Chem. Rev., 52, 81 (1953).

    Google Scholar 

  14. B. A. Arbuzov and V. S. Vinogradova, Proc. Acad. Sci., USSR, 50, 779, (1948)

    Google Scholar 

  15. B. A. Arbuzov and E. K. Yuldasheva, Proc. Acad. Sci., USSR, 70, 231 (1950).

    Google Scholar 

  16. K. A. Andrianov and M. V. Sobolevsky. Macromolecular Organosilicon Compounds, p. 310, Defense Press 1948.

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Atbuzov, U.A., Vinogradova, V.S. Parachors of trialkylmethylsilanes. Russ Chem Bull 4, 945–949 (1955). https://doi.org/10.1007/BF01172114

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  • DOI: https://doi.org/10.1007/BF01172114

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