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Esters of ethylphosphonous acid, and some of their reactions

Communication 6. Truthylphosphonamidous esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Triethylphosphonamidous hloride and alkyl triethylphosphonatnldites (ranging from the methyl to the decyl ester) were synthesized.

  2. 2.

    Triethylphosphoamidothloic chloride was prepared by addition of sulfur to triethylphosphonamidous chloride in presence of aluminum chloride.

  3. 3.

    Alkyl triethylphosphonamidothicate, (ranging from the methyl to the decyl ester) were ptepared by addition of sulfur to alkyl triethylphosphonamidites.

  4. 4.

    When trlethylphosphonamldous chloride was treated with as alcohol. the arnido group was eliminated In the form of diethylamine hydrochloride and a dialkyl ethylphosphonite was formed.

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Literature cited

  1. G. M. Koslapoff and R. M Watson. J. Am. Chem. Soc., No. 9, 73,4101 (1953).

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Authors and Affiliations

  1. Chemical Institute of the USSR Academy of Sciences, USSR

    B. A. Arbuzov, H. I. Rizpolcabearky & M. A. Zvereva

Authors
  1. B. A. Arbuzov
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  2. H. I. Rizpolcabearky
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  3. M. A. Zvereva
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Arbuzov, B.A., Rizpolcabearky, H.I. & Zvereva, M.A. Esters of ethylphosphonous acid, and some of their reactions. Russ Chem Bull 4, 935–943 (1955). https://doi.org/10.1007/BF01172113

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  • DOI: https://doi.org/10.1007/BF01172113

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