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Viscosity and structure of dialkylphosphorous acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Viscosity determinations on dialkylphosphorous acids in dilute carbon tetrachloride or benzene solution give value of ηequiv that indicate that these substances are in the monomeric condition.

  2. 2.

    By transesterification of diethylphosphorous acid by the appropriate alcohol the following substances have been synthesized for the first time: dinonyl-, didecyl-, dihexadecyl-, bis(β-phenylethyl)-, (ethyl)hexyl-, and (ethyl)octyl-phosphorous acids.

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Literature Cited

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Authors and Affiliations

  1. A. M. Butlerov Chemical Research Institute attached to the V. l. Ulyanov-Lenin Kazan State University, USSR

    B. A. Arbuzov & V. S. Vinogradova

Authors
  1. B. A. Arbuzov
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  2. V. S. Vinogradova
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Additional information

The original terminology is retained, dialkylphosphorous acid being a non-committal term for what may be a dialkyl phosphonate, a dialkyl hydrogen phosphite, or a tautomeric mixture of these-Publisher.

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Arbuzov, B.A., Vinogradova, V.S. Viscosity and structure of dialkylphosphorous acids. Russ Chem Bull 1, 485–489 (1952). https://doi.org/10.1007/BF01172002

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  • DOI: https://doi.org/10.1007/BF01172002

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