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New synthesis of [RhH{P(OPh)3}4] and related reactions

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Summary

A synthesis of [RhH{P(OPh)3}4] (1) from [Rh(acac){P(OPh)3}2] or [Rh(acac)(CO)2] has been developed. The reaction of theortho-metallated complex

(2) with H2, leading to (1) is described.

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Authors and Affiliations

  1. Institute of Chemistry, University of Wrocław, 50-383, Wrocław, Poland

    Anna M. Trzeciak & Józef J. Ziółkowski

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  1. Anna M. Trzeciak
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  2. Józef J. Ziółkowski
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Trzeciak, A.M., Ziółkowski, J.J. New synthesis of [RhH{P(OPh)3}4] and related reactions. Transition Met Chem 12, 408–409 (1987). https://doi.org/10.1007/BF01171649

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  • DOI: https://doi.org/10.1007/BF01171649

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