Skip to main content
SpringerLink
Log in

Heterocyclic analogs of pleiadiene. 63. Synthesis and crystal structure of 1-aminoperimidines

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By action of O-picrylhydroxylamine on perimidine and 2-methylperimidine, we have synthesized their 1-amino derivatives. An x-ray diffraction investigated of 1-aminoperimidine showed that the amino group in them is found in a pyramidal configuration with the axis of the unshared electron pair lying in the plane of the heterocyclic ring, oriented toward the μ-carbon atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A..Pozharskii, N. V. Vistorobskii, and V. S. Grigoryan, Zh. Org. Khim.,30, 923 (1994).

    Google Scholar 

  2. v. V. Kuzmenko and A. F. Pozharskii, Adv. Heterocycl. Chem.,53, 85 (1992).

    Google Scholar 

  3. V. V. Kuz'menko, T. A. Kuz'menko, G. G. Aleksandrov, A. F. Pozharskii, and A. V. Gulevskaya, Khim. Geterosikl. Soedin., No. 6, 836 (1987).

  4. A. F. Pozharskii, V. V. Kuzmenko, M. C. Foces-Foces, A. L. Llamas-Saiz, R. M. Claramunt, D. Sanz, and J. Elguero, J. Chem. Soc. Perkin II, No. 4, 841 (1994).

  5. M. C. Foces-Foces, F. H. Cano, R. M. Claramunt, D. Sanz, J. Catalan, F. Faber, A. Fruchier, and J. Elguero, J. Chem. Soc. Perkin II, No. 2, 237 (1990).

  6. T. A. Kuz'menko, V. V. Kuz'menko, A. F. Pozharskii, O. V. Kryshtalyuk, and G. G. Aleksandrov, Khim. Geterotsikl. Soedin., No. 2, 205 (1992).

  7. A. F. Pozharskii, Theoretical Principles of Heterocyclic Chemistry [in Russian], Khimiya, Moscow (1985), p. 72.

    Google Scholar 

  8. V. V. Kuz'menko, A. F. Pozharskii and V. N. Komissarov, Khim. Geterotsikl., Soedin., No. 1, 93 (1980).

  9. Y. Tamura, H. Tsubouchi, E. Doi, and M. Ikeda, Chem. Pharm. Bull.,31, 1378 (1983).

    Google Scholar 

  10. V. A. Myasnikov, I. L. Yudin, O. P. Shitov, and V. A. Tartakovskii, in: Abstracts, Fifth All-Union Conference on the Chemistry of Nitrogen-Containing Heterocyclic Compounds [in Russian], Chernogolovka (1991), Pt. 1, p. 147.

  11. R. Chidambaran, A. Sequerira, and S. K. Sikka, J. Chem. Phys.,41, 3616 (1964).

    Google Scholar 

  12. A. F. Pozarskii, I. S. Kashparov, P. J. Holls, and V. G. Zaletov, Khim. Geterotsikl. Soedin., No. 4, 543 (1971).

  13. W. Klyne and P. B. D. de la Mare, in: Progress in Sterochemistry [Russian translation], GNT1Khl. (1961), p. 547.

  14. Y. Tamura, J. Minamikawa, K. Sumoto, S. Fujii, and M. Ikeda, J. Org. Chem.,38, 1239 (1973).

    PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Rostov State University, Rostov-on-Don 344006

    A. F. Pozharskii, O. V. Kryshtalyuk, G. G. Aleksandrov & V. V. Kuz'menko

Authors
  1. A. F. Pozharskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Kryshtalyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. G. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Kuz'menko
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pozharskii, A.F., Kryshtalyuk, O.V., Aleksandrov, G.G. et al. Heterocyclic analogs of pleiadiene. 63. Synthesis and crystal structure of 1-aminoperimidines. Chem Heterocycl Compd 31, 92–98 (1995). https://doi.org/10.1007/BF01171300

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01171300

Keywords

Search

Navigation