Summary
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1.
It has been shown that in solution of cis- and trans-dichlorodiamineplatinums the presence of ultraviolet radiation leads to the formation of polynuclear compounds of bi- and quadri-valent platinum having hydroxyl bridges.
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2.
The active frequencies correspond to the absorption band of these compounds having a maximum at 2730 A.
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Literature cited
A. V. Nikolaev, Doctorate THesis (1940).
I. I. Chernyaev and M. M. Yakshin Bull. Sect. Platinum, No. 17 29 (1940).
I. Liefschitz and E. Rosenbohm, Z. Phys. Chem., 87, 1 (1921).
A. V. Babaeva, Proc. Acad. Sci. USSR, 4, 4, 167 (1943).
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Babaeva, A.V., Mosyagina, M.A. Reactions in solutions of bivalent platinum diammines in presence of ultraviolet radiation. Russ Chem Bull 2, 205–208 (1953). https://doi.org/10.1007/BF01170986
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DOI: https://doi.org/10.1007/BF01170986