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Ethylphosphonous esters and some of their reactions

Communication 9. Mixed anhydrides of ethylphosphonous acid and dialkyl hydrogen phosphites and the mixed anhydride of ethylphosphonous acid and isopropyl hydrogen ethylphosphonite. Diethyl ethylphosphonodithioite

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Mixed anhydrides of ethylphosphonousacid and dialkyl hydrogen phosphites were prepared.

  2. 2.

    It was shown that treatment of the mixed anhydrides with alkyl halides resulted in rearrangement with formation of quaternary phosphonium salts.

  3. 3.

    Diethyl ethylphosphonodithioite was prepared.

  4. 4.

    Diethyl ethylphosphonotrithioate was obtained by addition of sulfur to diethyl ethylphosphonodithioite.

  5. 5.

    It was found that treatment of diethyl ethylphosphonodithioite with benzyl bromide results in the formation of dibenzylethylpbosphine sulfide and ethyl benzylethylphosphinodithioate.

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Literature cited

  1. A. F. Divinsky, M. I. Kabachnik and V. V. Sidorenko, Proc. Acad. Sri. USSR 60, 999 (1948).

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Authors and Affiliations

  1. A. E. Arbuzov Chemical Institute of the Kazan Affiliated Institute of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, N. I. Rizpolozhensky & M. A. Zvereva

Authors
  1. B. A. Arbuzov
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  2. N. I. Rizpolozhensky
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  3. M. A. Zvereva
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Arbuzov, B.A., Rizpolozhensky, N.I. & Zvereva, M.A. Ethylphosphonous esters and some of their reactions. Russ Chem Bull 6, 189–195 (1957). https://doi.org/10.1007/BF01170552

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  • DOI: https://doi.org/10.1007/BF01170552

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