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Systems containing hydrogen peroxide at high concentration

Communication 13. Properties of peroxy compounds of zinc

  • Inorganic and analytical chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The solid phases found in the investigation of the system Zn(OH)2-H2O2-H2O are stable only when in equilibrium with the corresponding liquid phases. Only ZnO2 · 0.5 H2O was isolated as a chemical individual.

  2. 2.

    The final product of the dehydration of the various solid phases of the system is ZnO2 · 0.5H2O.

  3. 3.

    Further prolonged drying of ZnO2 · 0.5 H2O at 110° does not give anhydrous zinc peroxide, ZnO2, but is accompanied by decomposition of the peroxide.

  4. 4.

    Thermal analysis showed that ZnO2 · 0.5 H2O decomposes with elimination of H2O and active oxygen at 180–190°

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and inorganic chemistry of the Academy of Sciences of the USSR, USSR

    S. Z. Makarov, L. V. Ladeinova & A. F. Kapustinsky

Authors
  1. S. Z. Makarov
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  2. L. V. Ladeinova
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  3. A. F. Kapustinsky
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Makarov, S.Z., Ladeinova, L.V. & Kapustinsky, A.F. Systems containing hydrogen peroxide at high concentration. Russ Chem Bull 6, 147–150 (1957). https://doi.org/10.1007/BF01170547

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  • DOI: https://doi.org/10.1007/BF01170547

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