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Tetracyclic alkaloids of the sparteine group.1H and13C NMR spectroscopy and conformational analysis

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The1H and13C chemical shifts of 11 sparteine derivatives are reported. Substituent and group effects are interpreted in terms of structural properties. The conformational equilibrium of aphyllin is determined.

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Authors
  1. H. Duddeck
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  2. J. Skolik
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  3. U. Majchrzak-Kuczynska
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Additional information

Dedicated to Prof. N. S. Zefirov on the occasion of his 60th birthday.

Ruhr-Universität Bochum, Fakultät für Chemie, Bochum, Germany. Universität Hannover, Institut für Organische Chemie, Hannover, Germany (present address). Department of Organic Chemistry, Poznan Academy of Economics, Poznan, Poland. Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1026–1033, August, 1995. Original article submitted May 10, 1995.

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Duddeck, H., Skolik, J. & Majchrzak-Kuczynska, U. Tetracyclic alkaloids of the sparteine group.1H and13C NMR spectroscopy and conformational analysis. Chem Heterocycl Compd 31, 893–899 (1995). https://doi.org/10.1007/BF01170317

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