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Catalytic hydrocondensation of carbon monoxide with olefins communication 17. Participation of 2-butene in the hydrocondensation reaction with carbon monoxide

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The products of the hydrocondensation of carbon monoxide with 1-butene and with 2-butene are in both cases mainly normal aliphatic hydrocarbons admixed with a very small amount of slightly branched hydrocarbons.

  2. 2.

    In the hydrocondensation of carbon monoxide with 1-butene, a more unsaturated, lighter product is obtained than in the same reaction with 2-butene.

  3. 3.

    A comparison of our results on the two reactions enables us to infer that the mechanism is the same in both cases, but in the 2-butene reaction the 2-butene is largely isomerized into 1-butene, which then. undergoes hydrocondensation with carbon monoxide.

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Literature cited

  1. Ya. T. Eidus and R. I. Izmailov. Bull Acad. Sci. USSR, Div. Chem. Sci. 1956, 723 (T.p. 733).

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  2. Ya T. Eidus and R. I. Izmailov, Bull Acad. Sci. USSR, Div. Chem. Sci. 1956, 475 (T.p. 465).

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  3. Ya. T. Eidus and R. I. Izmailov, Bull Acad. Sci. USSR, Div. Chem. Sci. 1956, 467 (T.p. 457).

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  4. Ya. T. Eidus, N. D. Zelinsky, K. V Puzitsky and N. I. Enshov, Bull Acad. Sci. USSR, Div. Chem. Sci. 1952, 145 (T.p. 157).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    Ya T. Eidus & R. I. Izmailov

Authors
  1. Ya T. Eidus
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  2. R. I. Izmailov
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Eidus, Y.T., Izmailov, R.I. Catalytic hydrocondensation of carbon monoxide with olefins communication 17. Participation of 2-butene in the hydrocondensation reaction with carbon monoxide. Russ Chem Bull 5, 889–891 (1956). https://doi.org/10.1007/BF01169995

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  • DOI: https://doi.org/10.1007/BF01169995

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