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Polyorganostanno- and polyorganotitanosiloxanes

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The syntheses were effected of new polymeric substances, i. e., polyorganostannosiloxanes and poly organotitanosiloxanes, the chains of which contain not only siloxane links

    but also

    and

    links.

  2. 2.

    It was shown that

    and

    links in polyorganostanno- and polyorganotitanosiloxanes are broken down by strong sulfuric acid.

  3. 3.

    It was found that polyorganostanno- and polyorganotitanosiloxanes are soluble in organic solvents. The fractional compositions of these products were studied, and it was shown that they are cocondensation products.

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Literature cited

  1. K. A. Andrianov, Author's certificate No. 71115 of February 15, 1947.

  2. K. A. Andrianov, A. A. Zhdanov and S. A. Pavlov, Proc. Acad. Sci. USSR, 102, No. 1, 85 (1955).

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  3. K. A. Andrianov and T. N. Ganina, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956, 74 (T.p. 71).

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  4. K. A. Kocheshkov, Synthetic Methods in the Field of Organometallïc Compounds of Elements of Group IV (Acad. Sci. USSR Press, Moscow and Leningrad, 1947).

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  5. O. V. Nogina, R. Kh. Freidlina and A. N. Nesmeyanov, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1950, 327.

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Authors and Affiliations

  1. V. I. Lenin Electrotechnical Institute, Russia

    K. A. Andrianov, T. N. Ganina & E. N. Khrustaleva

Authors
  1. K. A. Andrianov
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  2. T. N. Ganina
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  3. E. N. Khrustaleva
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Andrianov, K.A., Ganina, T.N. & Khrustaleva, E.N. Polyorganostanno- and polyorganotitanosiloxanes. Russ Chem Bull 5, 817–822 (1956). https://doi.org/10.1007/BF01169985

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  • DOI: https://doi.org/10.1007/BF01169985

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