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Gas chromatographic determination of the free energy of sorption of methylene units ofN-alkylsubstituted six-membered cyclic amines

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The free energy of sorption of methylene units, ΔG(CH2), for the homologous series ofN-alkylsubstituted morpholines, thiomorpholines, piperidines and 2-methyl-, 3-methyl-, 4-methyl- and 2,6-dimethylpiperidines was determined. It was shown that the dependence of these values on the number of CH2 units in the carbon chain is not linear. Universal equations for calculating the values of the energy contribution depending on the number of CH2 units in the carbon chain were obtained. Abnormally high values of free energy of sorption of the first CH2 unit were found in all series studied and reasons for the anomaly are discussed.

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Authors and Affiliations

  1. Institute of Food Substances, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    I. L. Zhuravleva, R. V. Golovnya, M. B. Terenina & T. E. Kuz'menko

Authors
  1. I. L. Zhuravleva
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  2. R. V. Golovnya
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  3. M. B. Terenina
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  4. T. E. Kuz'menko
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 437–439, March, 1994.

This work was made possible by the financial support of Russian Foundation for Basic Research, project No. 93-03-4969,

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Zhuravleva, I.L., Golovnya, R.V., Terenina, M.B. et al. Gas chromatographic determination of the free energy of sorption of methylene units ofN-alkylsubstituted six-membered cyclic amines. Russ Chem Bull 43, 395–397 (1994). https://doi.org/10.1007/BF01169713

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  • DOI: https://doi.org/10.1007/BF01169713

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