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Synthesis and characterization of the undecaosmium carbido carbonyl cluster: Crystal and molecular structures of [N(PPh3)2][Os11C(CO)27(μ-Cl)]

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Abstract

A chloro-derivative of undecaosmium carbido cluster [Os11C(CO)27(µ-Cl)]-1 anion has been prepared and fully characterized by spectroscopic and crystallographic methods. The structure1 is an important intermediate for the conversion of [Os11C(CO)27]2 2 dianion to [OS10C(CO)24]2-3 dianion.

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References

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Author notes

  1. Wing-Tak Wong

    Present address: Centre for Materials Science, The University of Hong Kong, Pokfulam Road, Hong Kong

Authors and Affiliations

  1. Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong

    Wing-Tak Wong

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  1. Wing-Tak Wong
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Wong, WT. Synthesis and characterization of the undecaosmium carbido carbonyl cluster: Crystal and molecular structures of [N(PPh3)2][Os11C(CO)27(μ-Cl)]. J Clust Sci 6, 343–346 (1995). https://doi.org/10.1007/BF01169700

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  • DOI: https://doi.org/10.1007/BF01169700

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