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Synthesis and transformations of unsaturated organosilicon compounds Communication 2. Synthesis of tertiary trihydricγ-silicon-containing alcohols of the acetylenic series

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The interaction of trichlorosilane, methyltrichlorosilane and vinyltrichlorosilane with the mixed alcoholate of dimethylethynyl carbinol-magnesium bromide was investigated. The reactions yielded three representatives of a new class of organosilicon compounds - trihydric tertiaryγ-silicon-containing alcohols of the acetylenic series.

  2. 2.

    A method of preparation of trihydric tertiaryγ-silicon-containing acetylenic alcohols was developed on the basis of the reaction of alkyltrichlorosilanes with dimethylethynyl carbinol-magnesium bromide.

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Literature cited

  1. M. F. Shostakovsky, I. A. Shikhiev, and N. V. Komarov, Proc. Acad. Sci. USSR 109, 3, 344 (1956).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences, USSR

    I. A. Shikhtev, M. F. Shostakovsky, N. V. Komarov & L. A. Kayutenko

Authors
  1. I. A. Shikhtev
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  2. M. F. Shostakovsky
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  3. N. V. Komarov
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  4. L. A. Kayutenko
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Shikhtev, I.A., Shostakovsky, M.F., Komarov, N.V. et al. Synthesis and transformations of unsaturated organosilicon compounds Communication 2. Synthesis of tertiary trihydricγ-silicon-containing alcohols of the acetylenic series. Russ Chem Bull 6, 1168–1171 (1957). https://doi.org/10.1007/BF01169403

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  • DOI: https://doi.org/10.1007/BF01169403

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