Summary
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1.
The action of ethylamine, aniline or diethylamine on phenylboron dichloride leads to formation of N-substituted phenyldiaminoborons.
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2.
Heating of phenyldi(ethylamino)boron converts it into B-triphenyl-N-Uiethylborazole.
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3.
Heating of phenyldi(phenylamino)boron converts it into hexaphenylborazole.
Literature cited
R. Jones and C. Kinney, J. Am. Chem. Soc. 61, 1378 (1939).
B. M. Mikhailov and T. V. Kostroma, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956; 1144.
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Mikhailov, V.M., Aronovich, P.M. Organoboron compounds Communication 20. N-substituted phenyldiaminoborons and B-phenylborazoles. Russ Chem Bull 6, 1146–1148 (1957). https://doi.org/10.1007/BF01169396
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DOI: https://doi.org/10.1007/BF01169396