Skip to main content
SpringerLink
Log in

Oxidation-reduction systems for initiating radical processes 6. Systems with participation of oxygen for initiation of the process of oxidative breakdown of polymers

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the mechanism of the action of various oxidation-reduction systems containing organic reducing agents, salts of iron, and oxygen; it was shown that in hydrocarbon media they are active sources of free radicals at low temperatures.

  2. 2.

    The possibility of employing such systems for initiation of a chain process of oxidative destruction of unsaturated and some saturated polymers at low temperatures was demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. E. I. Tinyakova, B. A. Dolgoplosk, and V. N. Reikh, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1957, 851.

  2. J. H. Walton and G. W. Filson, J. Am. Chem. Soc. 54, 5228 (1932).

    Google Scholar 

  3. W. G. Gormley, Chem. Met. Eng. 53, 4, 208 (1946); J. Chem. Ind. 7, 29 (1947);

    Google Scholar 

  4. A. Bertho and C. Glück, Ann. 494, 159 (1932); S. Hussak, Z. Physiol. Chem. 247, 239 (1937).

    Google Scholar 

  5. D. M. Mikhlin, Peroxides and Peroxidases, Acad. Sci. USSR Press, 1948

  6. J. Williams and C. C. Smith, Ind. Eng. Chem. 27, 1317 (1935); B. A. Dogadkin, Chemistry and Physics of Rubber, State Chem. Press, 1947, p. 291.

    Google Scholar 

  7. B. A. Dolgoplosk, D. Sh. Korotkina, and G. A. Parfenova, Symposium “Problems of the Chemical Kinetics of Catalysis and Reactivity,” Acad. Sci. USSR Press, 1953, p. 303.

  8. B. A. Dolgoplosk, V. A. Krol, S. E. Bresler, and S. Ya. Frenkel, J. Gen. Chem. 26, 2201 (1956).

    Google Scholar 

  9. L. M. Romanov, B. A. Dolgoplosk, and B. L. Erusalimsky, Proc. Acad. Sci. USSR 105, 298 (1955).

    Google Scholar 

  10. W. C. Bray and M. H. Gorin, J. Am. Chem. Soc. 54, 2124 (1932).

    Google Scholar 

  11. W. Manchot and O. Willhelms, Ber. 34, 2479 (1901).

    Google Scholar 

  12. F. Haber and H. Weiss, Proc. Roy. Soc. A. 147, 332 (1934).

    Google Scholar 

  13. E. I. Tinyakova, B. A. Dolgoplosk, and M. B. Rabinovich, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1957, 702.

  14. B. A. Dolgoplosk and E. N. Kropacheva, J. Gen. Chem. 26, 2890 (1956)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of High-Molecular Compounds of the Academy of Sciences of the USSR, USSR

    E. I. Tinyakova, B. A. Dolgoplosk & V. N. Reikh

Authors
  1. E. I. Tinyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. A. Dolgoplosk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. N. Reikh
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tinyakova, E.I., Dolgoplosk, B.A. & Reikh, V.N. Oxidation-reduction systems for initiating radical processes 6. Systems with participation of oxygen for initiation of the process of oxidative breakdown of polymers. Russ Chem Bull 6, 1135–1143 (1957). https://doi.org/10.1007/BF01169394

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01169394

Keywords

Search

Navigation