Summary
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1.
Three out of the five possible bis-(trimethyls lyl)propylenes were synthesized.
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2.
It was established that quinoline splits off only theβ-chlorine atom fromα,β-dichloropropyltrichloro-silane with formation of Cl3SiCCl = CHCH3 Quinoline splits off theα-chlorine atom fromα, β-dichloroisopro-pyltrichlorosilane with formation of
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3.
β,γ-Dichloropropyltrichlorosilane is found to lose HCI when distilled in presence of AlCl3, forming onlyγ-chloroallyltrichlorosilane.
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Petrov, A.D., Mironov, V.F., Glukhovtsev, V.G. et al. Synthesis and properties of some bis-(trim ethyls ilyl)propylenes. Russ Chem Bull 6, 1117–1125 (1957). https://doi.org/10.1007/BF01169391
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DOI: https://doi.org/10.1007/BF01169391