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Mixed ferrocyanides of indium with rubidium and cesium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The systems InCl3-Rb4 [Fe (CN)6]-H2O and InCl3-Cs4 [Fe (CN)6]-H2O were studied by the methods of solubility, electrical conductivity, and potentiometric and light-extinction measurements.

  2. 2.

    In the system InCl3-Rb4 [Fe (CN)6]-H2O indium ions are found to react with formation of solid solutions and a mixed ferrocyanide with the composition Rbln [Fe (CN)6].

  3. 3.

    The mixed ferrocyanide Csln [Fe (CN)6] is formed in the system InCl3-Cs4 [Fe (CN)6]-H2O; a solid solution is also formed and (with suitable ratios of components) a second mixed ferrocyanide Cs7In3 [Fe (CN)6]4.

  4. 4.

    Indium ferrocyanides were analyzed by chemical, crystallographic and x-ray methods.

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Literature cited

  1. E. N. Deichman and I. V. Tananaev, Chemistry of Rare Elements, 1955, p. 2, 37.

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  3. J. Mitchell and D. Smith, Aquametry (Foreign Lit. Press, Moscow, 1952), p, 27.

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  4. I. V. Tananaev and M. I. Levina, J. Appl. Chem. 17, 356 (1944).

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  5. V. G. Kuznetsov, Report of Institute of General and Inorganic Chemistry, 1956.

  6. E. N. Deichman and I. V. Tananaev, Volumetric and Colorimetric Methods of Determination of Indium, Report of Institute of General and Inorganic Chemistry 1, 1.956.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences, USSR

    E. N. Deichman

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  1. E. N. Deichman
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Deichman, E.N. Mixed ferrocyanides of indium with rubidium and cesium. Russ Chem Bull 6, 1044–1051 (1957). https://doi.org/10.1007/BF01169380

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  • DOI: https://doi.org/10.1007/BF01169380

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